Quantifying solvated electrons' delocalization
نویسندگان
چکیده
منابع مشابه
Quantifying solvated electrons' delocalization.
Delocalized, solvated electrons are a topic of much recent interest. We apply the electron delocalization range EDR(r;u) (J. Chem. Phys., 2014, 141, 144104) to quantify the extent to which a solvated electron at point r in a calculated wavefunction delocalizes over distance u. Calculations on electrons in one-dimensional model cavities illustrate fundamental properties of the EDR. Mean-field ca...
متن کاملElectrogenerated chemiluminescence. 39. Reactions of solvated electrons in liquid ammonia
The Journal of Physical Chemistry is published by the American Chemical Society. 1155 Sixteenth Street N.W., Washington, DC 20036 Electrogenerated chemiluminescence. 39. Reactions of solvated electrons in liquid ammonia Kingo Itaya, and Allen J. Bard J. Phys. Chem., 1981, 85 (10), 1358-1365• DOI: 10.1021/j150610a018 • Publication Date (Web): 01 May 2002 Downloaded from http://pubs.acs.org on Fe...
متن کاملDispersion Stabilization of Solvated Electrons and Dipole-Bound Anions
It has long been assumed that stability of “solvated electrons” and dipole-bound anions results primarily from the static Coulomb interaction of an excess electron with charge distribution of the neutral molecular host. Our results indicate, however, that the dispersion interaction between the loosely bound electron and the neutral molecular host is as important as the static Coulomb stabilizat...
متن کاملAngle-Resolved Photoemission of Solvated Electrons in Sodium-Doped Clusters.
Angle-resolved photoelectron spectroscopy of the unpaired electron in sodium-doped water, methanol, ammonia, and dimethyl ether clusters is presented. The experimental observations and the complementary calculations are consistent with surface electrons for the cluster size range studied. Evidence against internally solvated electrons is provided by the photoelectron angular distribution. The t...
متن کاملDelocalization of Electrons in Strong Insulators at High Dynamic Pressures
Systematics of material responses to shock flows at high dynamic pressures are discussed. Dissipation in shock flows drives structural and electronic transitions or crossovers, such as used to synthesize metallic liquid hydrogen and most probably Al₂O₃ metallic glass. The term "metal" here means electrical conduction in a degenerate system, which occurs by band overlap in degenerate condensed m...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Physical Chemistry Chemical Physics
سال: 2015
ISSN: 1463-9076,1463-9084
DOI: 10.1039/c5cp01967b